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tert-Butyl 2-ethylhexyl peroxydicarbonate (TBEC) 34443-12-4

2022-11-09tbec
Product Information:
  • Product Name: Initiator TBEC
  • English Name: Tert-butylperoxy 2-ethylhexyl carbonate
  • Chemical Name: Tert-butylperoxy-2-ethylhexyl carbonate
  • Molecular Formula: C13H26O4
  • Molecular Weight: 246.3
  • Theoretical Active Oxygen Content: 6.49%
  • CAS Number: 34443-12-4
  • EINECS Number: 252-029-5
Major decomposition products:
  • Carbon dioxide (CO₂)
  • tert-Butanol
  • 2-Ethylhexanol
Safety Data:
  • Half-life (measured in a chlorobenzene solution):
    • 0.1 hour: 137°C
    • 1 hour: 117°C
    • 10 hours: 98°C
Thermal Stability Data:
  • Self-accelerating decomposition temperature (SADT): 60°C
Technical Specifications:
  • Appearance: Colorless, clear liquid
  • Purity: ≥95.0%
  • Color: < 50 Pt-Co
  • TBHP Content: < 1000 mg/kg
  • Inorganic and organically hydrolyzable chlorine: < 100 mg/kg
Packaging:
  • Standard Packaging: 25 kg net weight PE plastic drum
  • Packaging complies with UN Number 3105 and is classified as Class 2 dangerous goods packaging
Safety Precautions:
  1. Keep away from sources of ignition, open flames, and heat.
  2. Avoid contact with reducing agents (such as amines), acids, alkalis, and heavy metal compounds (such as accelerators, metal soaps, etc.).
  3. Please refer to the Material Safety Data Sheet (MSDS) for this product before use.
Applications:
  1. Styrene Polymerization: Suitable for the polymerization of styrene and styrene copolymers at temperatures ranging from 100 to 130°C.In bulk polymerization, TBEC helps increase the reaction rate. In aqueous suspension polymerization processes, the use of TBEC can reduce the residual amount of styrene monomer in the final stage of the reaction.
  2. Polymerization of Acrylates and Methacrylates: Suitable for the polymerization of acrylates or methacrylates at temperatures ranging from 100 to 170°C.
  3. Curing of thermosetting resins: Suitable for the curing of aliphatic unsaturated polyesters at high temperatures. TBEC is the preferred curing agent for the hot compression molding process of UP resins (SMC, BMC, ZMC, etc.), with a temperature range of 120–170°C. The resulting products are heat-resistant, safe, and environmentally friendly.
Storage Conditions:
  • Keep the packaging tightly sealed and store in a well-ventilated area
  • Maximum storage temperature: 25°C
  • Avoid contact with reducing agents such as amines, acids, alkalis, and heavy metal compounds (accelerators and metal soaps)
  • Do not repackage or handle the product within the warehouse
Storage Stability:
  • When stored under the conditions specified by the manufacturer, the product is guaranteed to meet factory technical standards for three months.
Fire Extinguishing:
  • For small fires, use a dry powder or carbon dioxide fire extinguisher, while simultaneously spraying with copious amounts of water to prevent reignition.
  • For large fires, spray a large volume of water from a safe distance.

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