Product Information:
- Product name: Perkadox 16
- Chemical composition: Di(4-tert-butylcyclohexyl) peroxydicarbonate
- CAS No. 15520-11-3
- EINECS/ELINCS No. 239-557-1
- Molecular weight: 398.5
- Appearance: white powder
- Content: 94.0-97.0%
- Density: 1.13 g/cm³ (20°C)
- Bulk density: 450-480 kg/m³ (20°C)
Properties and Applications:
- Thermoset Composites: Perkadox® 16 is a solid peroxydicarbonate used primarily for curing unsaturated polyester and methacrylic resins at temperatures of 60°C and higher. Perkadox® 16 is not suitable for the production of clear castings or coatings as it can lead to cloudy final products. For transparent products it is recommended to use Perkadox® 16S . Perkadox® 16 exhibits high reactivity at elevated temperatures due to the low activation temperature of Perkadox® 16 as well as its long service life at room temperature.Perkadox® 16 is usually combined with less reactive peroxides such asTrigonox CTrigonox 29-B50. Trigonox 21S maybePerkadox® GB-50XUse together to ensure good curing. Ideal for applications where long gel times or production times are required at room temperature and fast curing at 60-140°C. Examples: pultrusion molding, fiber winding, artificial marble production, etc.
- Polymer Production: Polymerization of Vinyl Chloride: Perkadox® 16 can be used for suspension and intrinsic polymerization of Vinyl Chloride at temperatures in the range of 40-65°C. It can also be used as a polymerization agent for the polymerization of vinyl chloride. Perkadox® 16 can be used alone or in combination with other peroxides such as 1,1,3,3-tetramethylbutyl peroxyneodecanoate (Trigonox 423), isopropylphenyl peroxyneodecanoate (Trigonox 99) or peroxydilauroyl (Laurox) are used in tandem to increase reactor efficiency.
- Acrylic Resin Production: Perkadox® 16 is an initiator for the (co-)polymerization of methacrylates and acrylates.
Half-life and thermal stability:
- The half-life of Perkadox 16 in chlorobenzene was 0.1 h (82°C), 1 h (64°C) and 10 h (48°C) at different temperatures.
- Thermally unstable with a self-accelerating decomposition temperature (SADT) of 40°C.
- Maximum storage temperature is 20°C.
Packaging and transportation:
- The standard packaging is 20kg carton, in compliance with international regulations.
- Perkadox 16 is a Class C organic peroxide, solid, temperature controlled, Class 5.2; UN3114.
Security and handling:
- Keep container tightly closed during storage and operation, store in a dry, well-ventilated place, away from heat or ignition sources, and avoid direct sunlight.
- Prohibit weighing and dispensing in the storage room and avoid contact with reducing agents, acids, alkalis and heavy metal compounds.
- Detailed safety information can be found in the Safety Data Sheet (MSDS).
Main decomposition products:
- Carbon dioxide and 4-tert-butylcyclohexanol.