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Substance Index

Tert-Amyl Hydroperoxide

TAHPCAS 3425-61-44 brands · 6 models

Substance Identity

Chemical name
Tert-Amyl Hydroperoxide
Formula
C5H12O2
Molecular weight
104.1
CAS number
3425-61-4
Theoretical active oxygen
15.36%
Abbreviation
TAHP

Safety Data

Half-life temperature

0.1 hour

202°c

1 hour

183°c

10 hours

165°c

Self-accelerating decomposition temp. (SADT)
80°C

Cross-Brand Model Reference

Grades sharing this CAS are interchangeable in most formulations. Re-check assay, carrier and half-life before switching.

Applications

  • TAHP is a commonly used initiator for radical reactions. It is characterized by good thermal stability, safe handling, and ease of control. At temperatures b...
  • , its activity remains stable for three months without significant change, and it does not require costly frozen storage. It can be used in emulsion polymeri...
  • outperforms persulfates, isopropylbenzene hydroperoxide, and benzoyl peroxide in many respects. The decomposition products of TAHP are primarily tert-butanol...
  • most other initiators form acidic byproducts.
  • TAHP is also widely used as a polymerization initiator for styrene and styrene copolymers (such as SAN and ABS), as well as for acrylic acid, methacrylic aci...
  • TAHP is a very important organic synthesis intermediate.

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