United Initiators TMCH-90-AL 1,1-Di(tert.butylperoxy)-3,3,5-trimethylcyclohexane 6731-36-8

Product Information:

  • Product Name: TMCH-90-AL
  • Chemical composition: 1,1-Bis(tert.butyl peroxy)3,3,5-trimethyl cyclohexane
  • Molecular weight: 302.4 g/mol
  • Solubility: 90% is soluble in aliphatic hydrocarbons.

Description:

  • TMCH-90-AL is a colorless, easy-flowing liquid containing 90%'s 1,1-Bis(tert.butylperoxy)3,3,5-trimethyl cyclohexane, which is inhibited via aliphatic hydrocarbons. This cycloaliphatic hydrocarbon peroxide is mainly used as an initiator (source of free radicals) for the polymerization of monomers (e.g. styrene) as well as for the curing and polymerization of unsaturated polyester resins.

Technical data:

  • Appearance: colorless liquid
  • Peroxide content: approx. 90% w/w
  • Active oxygen content: approx. 9.5% w/w
  • Inhibitors: High-boiling aliphatic hydrocarbons
  • Density (20°C): approx. 0.895 g/cm³.
  • Viscosity (20°C): approx. 18 mPa-s
  • Refractive index (20°C): approx. 1.438
  • SADT: approx. 60°C
  • Refrigeration stability: below -25°C
  • Recommended storage temperature: below 30°C
  • Storage stability (active): 6 months from date of delivery

Areas of application:

  • Vinyl: initiator for high pressure vinyl polymerization, used with other peroxides of different activity. Temperature range: 200-250°C. Main advantages include: liquid, even at low and high pressures, insensitive to other components of the polymerization process.
  • Styrene: Used in the polymerization of styrene, either in bulk or solution polymerization, and copolymerization with other monomers such as butadiene and acrylonitrile. Temperature range: 100-140°C. Suggested dosage: 0.02-0.11 TP3T as supplied. Main advantages include: reduced residual monomer content, no reaction with chain modifiers (e.g. mercapto compounds), no hydrolysis in alkaline media.
  • Other monomers: For polymerization of vinyl acetate and (meth)acrylate. Temperature range: 90-130°C. Suggested dosage: 0.05-1% as supplied.

Packaging:

  • Standard packaging is HDPE drums of 25 kg each.

Disclaimer:

  • The information and technical advice provided is based on in-house testing of local raw materials and is intended to inform the user about products and applications. The information should not be construed as a guarantee of the specific performance of the products described or their suitability for a particular application, nor does it provide complete instructions for use. This information does not give any guarantee of the performance and storage stability of the products, nor does it assume any responsibility for any intellectual property rights, in particular with regard to patents. The company reserves the right to make any changes in accordance with technical progress or subsequent developments. Applications and usage of our products based on our technical recommendations are beyond our control and are entirely the responsibility of the user. It is the responsibility of the user to carry out careful inspection and testing of incoming goods to verify their suitability for the intended application.

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