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United Initiators CUROX®M-102 Methyl ethyl ketone peroxide 1338-23-4

2023-10-11curoxm-102
CUROX® M-102 is a methyl ethyl ketone peroxide used as a curing agent for unsaturated polyester resins and vinyl ester resins. The following is key information about this product: Appearance and Composition:
  • Appearance: Colorless liquid.
  • Active oxygen content: Approximately 8.6% w/w.
  • Antisensitizer: Fatty acid esters are used.
  • Density (20°C): Approximately 1.01 g/cm³.
  • Viscosity (20°C): Approximately 13 mPa·s.
  • Solubility: Insoluble in water; miscible with esters, unsaturated polyesters, and vinyl ester resins.
  • Critical temperature (SADT): Approximately 60°C.
  • Cold storage stability: Remains liquid below -25°C.
  • Recommended storage temperature: below 30°C.
  • Shelf life at 30°C is 6 months from the date of delivery.
Applications:
  • Primary Use: For curing large molded parts at room temperature in conjunction with a cobalt catalyst.
  • Suitable for curing unsaturated polyester resins; compatible with all types of unsaturated polyester resins and vinyl ester resins.
  • Standard dosage: 1–3% of the resin weight, combined with 0.5–2% of a 1% cobalt solution (or an alternative cobalt amine catalyst).
  • The “pot life” (gel time of resin + peroxide) is typically only a few hours, depending on temperature and resin type.
  • The “dormancy period” (gel time of resin + peroxide + catalyst) is relatively long, particularly when curing isophthalic or terephthalic resins.
Curing Properties:
  • Moderate heat release results in low internal stress.
  • Recommended for vinyl ester (VE) resins.
  • Relatively short demolding time, i.e., good demolding factor (fMR = tMR/tgel).
  • Temperatures below 20°C and/or certain specialized resin types can significantly delay curing; it is recommended to use more reactive grades of unsaturated polyester resins (CUROX M-202, 302, 402); for VE resins, add an amine catalyst.
Processing Methods:
  • Particularly suitable for hand lay-up, spray lay-up, centrifugal casting, fiber winding, resin casting, and surface coatings (fillers, fillers, gel coats, and topcoats).
Spray Equipment:
  • Use spray equipment in accordance with the manufacturer’s instructions. Ensure that all safety devices are functioning properly. Do not clean the spray gun by spraying MEKP into the air.
Measuring Activity:
  • Conduct a “cobalt cure” test at 25°C using OPA resin (20 g in a test tube).
Packaging:
  • CUROX® M-102 is available in standard packaging sizes of 5 kg and 22.5 kg polyethylene bottles.

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